Search results for "Inverse photoemission spectroscopy"

showing 10 items of 31 documents

Time-of-flight photoemission electron microscopy – a new way to chemical surface analysis

2001

Abstract The time structure of synchrotron radiation at BESSY I (Berlin) was utilised to operate a photoemission electron microscope in the time-of-flight mode. The electrons that are emitted from the sample surface with different energies are dispersed in a drift tube subsequent to the imaging optics. Two ways of fast image detection have been explored, a fast gated intensified CCD camera (800 ps gate time) and a special counting electronics in combination with a 3D (x,y,t)-resolving delay line detector ( time resolution ps). The latter device has a lateral resolution of about 50 μm in the image plane being equivalent to 1000 pixels along the image diagonal. An energy resolution of 400 meV…

Chemistrybusiness.industryInverse photoemission spectroscopyResolution (electron density)Synchrotron radiationSurfaces and InterfacesElectronImage planeCondensed Matter PhysicsSurfaces Coatings and FilmsPhotoemission electron microscopyTime of flightOpticsMaterials ChemistryImage sensorbusinessSurface Science
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Quantitative microscopy of magnetic domains in Fe(100) by core-level x-ray photoelectron spectroscopy

2005

We present an experimental technique for imaging of magnetic domain patterns based on element-specific core-level photoemission using polarized soft-x-ray radiation. It is applied to the measurement of domain patterns at the Fe(100) surface and at the surface of polycrystalline Fe. Different from well established imaging techniques that use a photoemission electron microscope to measure the secondary electron intensity at the Fe absorption threshold, we have investigated the photoemission intensity contrast on the the Fe $2{p}_{3∕2}$ core level using circularly polarized x-ray light. The linear and circular dichroism characteristics of the identical domain pattern are extracted by linear co…

Circular dichroismMagnetizationNuclear magnetic resonanceMaterials scienceX-ray photoelectron spectroscopyMagnetic domainInverse photoemission spectroscopyAngle-resolved photoemission spectroscopyCondensed Matter PhysicsMolecular physicsSecondary electronsCircular polarizationElectronic Optical and Magnetic MaterialsPhysical Review B
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Circular dichroism in angular resolved photoemission from pure and Rb-doped C60 and C22H14 layers on platinum and tungsten

1997

Abstract Polycrystalline C60 and Pentacene films grown on W(110) and Pt(111) have been studied in valence band photoemission using circularly polarised synchrotron radiation from BESSY with special emphasis on circular dichroism in photoemission. For thin films of C60, dichroic asymmetries of about 10% occur independent of the temperature and the substrate hinting that the rotation of the topmost layer is hindered even at room temperature. For Pentacene we found asymmetries up to 50% in the region of the σ-electrons. Moreover, we found for this molecule a dichroic asymmetry in normal emission, that is a forbidden geometry. This hints on adsorption with the molecules perpendicularly oriented…

Circular dichroismValence (chemistry)Binding energyInverse photoemission spectroscopyMetals and Alloyschemistry.chemical_elementSurfaces and InterfacesElectronic structureDichroismSurfaces Coatings and FilmsElectronic Optical and Magnetic MaterialsRubidiumPentacenechemistry.chemical_compoundchemistryMaterials ChemistryAtomic physicsThin Solid Films
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Valence band photoemission from thin iron films - A comparison of experimental and theoretical results

1998

Abstract In this contribution, we report on photoemission data from thin iron films on W(110) that have been carried out by means of spin-resolved photoelectron spectroscopy as well as Magnetic Circular Dichroism in valence band photoemission at the storage ring BESSY. These techniques give complementary information on the electronic and magnetic properties, such as exchange and spin–orbit splitting. We compare our experimental data to new photoemission calculations, which have been obtained in the framework of a fully relativistic one-step theory for ferromagnetic materials.

Condensed matter physicsChemistryMagnetic circular dichroismInverse photoemission spectroscopyAnalytical chemistryAngle-resolved photoemission spectroscopySurfaces and InterfacesCondensed Matter PhysicsSurfaces Coatings and FilmsCondensed Matter::Materials ScienceTransition metalX-ray photoelectron spectroscopyFerromagnetismCondensed Matter::SuperconductivityMaterials ChemistryCondensed Matter::Strongly Correlated ElectronsThin filmStorage ring
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Probing bulk electronic structure with hard X-ray angle-resolved photoemission.

2010

Traditional ultraviolet/soft X-ray angle-resolved photoemission spectroscopy (ARPES) may in some cases be too strongly influenced by surface effects to be a useful probe of bulk electronic structure. Going to hard X-ray photon energies and thus larger electron inelastic mean-free paths should provide a more accurate picture of bulk electronic structure. We present experimental data for hard X-ray ARPES (HARPES) at energies of 3.2 and 6.0 keV. The systems discussed are W, as a model transition-metal system to illustrate basic principles, and GaAs, as a technologically-relevant material to illustrate the potential broad applicability of this new technique. We have investigated the effects of …

DiffractionPhysicsPhotonPhotoemission spectroscopyMechanical EngineeringInverse photoemission spectroscopyAngle-resolved photoemission spectroscopyGeneral ChemistryElectronic structureElectronCondensed Matter PhysicsMechanics of MaterialsGeneral Materials ScienceWave vectorAtomic physicsNature materials
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Internal photoemission in solar blind AlGaN Schottky barrier photodiodes

2005

We have analyzed the photoresponse of solar blind AlGaN Schottky barrier photodiodes below the alloy band gap energy, in the 3.5-4.5 eV range, and we show that it is dominated by internal photoemission. The n-type Schottky barrier height is shown to increase linearly with the band gap energy of the AlGaN alloy. The amplitude of the internal photoemission signal is about 20 times smaller than the value given by the Fowler theory based on a free electron model. We explain this result by taking into account the interband transitions and the ballistic transport of photoexcited electrons in the metal. This low value of internal photoemission allows us to achieve a spectral rejection ratio betwee…

Free electron modelMaterials scienceFLAME DETECTIONPhysics and Astronomy (miscellaneous)business.industryBand gapSchottky barrierInverse photoemission spectroscopyPhotodetectorsWide-bandgap semiconductorSchottky diodeultraviolet photodetectorsGallium nitridePERFORMANCEFILMSPhotodiodelaw.inventionHEIGHTlawBallistic conductionOptoelectronicsHOT-ELECTRONSbusinessApplied Physics Letters
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Optical magnetic circular dichroism in threshold photoemission from a magnetite thin film

2011

Threshold photoemission excited by polarization-modulated ultraviolet femtosecond laser light is exploited for phase-sensitive detection of magnetic circular dichroism (MCD) for a magnetite thin film. Magnetite (Fe(3)O(4)) shows a magnetic circular dichroism of ∼(4.5 ± 0.3) × 10(-3) for perpendicularly incident circularly polarized light and a magnetization vector switched parallel and antiparallel to the helicity vector by an external magnetic field. The asymmetry in threshold photoemission is discussed in comparison to the magneto-optical Kerr effect. The optical MCD contrast in threshold photoemission will provide a basis for future laboratory photoemission studies on magnetic surfaces.

Magnetic circular dichroismChemistryInverse photoemission spectroscopyAnalytical chemistryPhysics::OpticsAngle-resolved photoemission spectroscopyCondensed Matter PhysicsMolecular physicsMagnetic fieldCondensed Matter::Materials ScienceMagnetizationX-ray magnetic circular dichroismCondensed Matter::SuperconductivityVibrational circular dichroismGeneral Materials ScienceCircular polarizationJournal of Physics: Condensed Matter
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Observation of quantized subband states and evidence for surface electron accumulation in CdO from angle-resolved photoemission spectroscopy

2008

The electronic structure of well-ordered single-crystal thin films of CdO100 has been studied using angleresolved photoemission spectroscopy. Quantized electron subbands are observed above the valence-band maximum. The existence of these states provides evidence of an intrinsic electron accumulation space-charge layer near the CdO surface, an interpretation supported by coupled Poisson-Schrodinger calculations. The origin of the accumulation layer result is discussed in terms of the bulk band structure of CdO calculated using quasiparticle-corrected density-functional theory, which reveals that the conduction-band minimum at the Brillouin-zone center lies below the charge neutrality level.

Materials scienceCondensed matter physicsPhotoemission spectroscopyInverse photoemission spectroscopyAngle-resolved photoemission spectroscopyElectronElectronic structureThin filmCondensed Matter PhysicsElectronic band structureLayer (electronics)Electronic Optical and Magnetic MaterialsPhysical Review B
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Magnetic dichroism in photoemission with unpolarized light.

1994

A magnetic dichroism in photoemission from ferromagnets induced by unpolarized light is observed for the first time in the valence band region as well as for surface states. The study was carried out with magnetized Fe(110), Co(0001), and Gd(0001) films grown epitaxially on W(110). This phenomenon leads to an intensity asymmetry for opposite directions of the sample magnetization. It can be easily used for a routine laboratory diagnostic of magnetic behavior. A simple theoretical interpretation of the phenomenon based on the atomic model is given.

Materials scienceCondensed matter physicsmedia_common.quotation_subjectInverse photoemission spectroscopyGeneral Physics and AstronomyAngle-resolved photoemission spectroscopyDichroismAsymmetryCondensed Matter::Materials ScienceMagnetizationNuclear magnetic resonanceFerromagnetismAtomic modelSurface statesmedia_commonPhysical review letters
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X-ray photoemission studies of the electronic structure of single-crystalline CdO(100)

2007

The electronic structure of single-crystalline CdO is investigated using X-ray photoemission spectroscopy. The surface is prepared by in situ Ar+ ion bombardment and annealing (IBA). The core level spectra before and after the IBA are presented, and reveal a dramatic reduction in the surface contamination. The semi-core Cd 4d level and valence band region following the IBA are also shown. The surface Fermi level is pinned 1.3 +/- 0.10 eV above the valence band maximum. (c) 2007 Elsevier Ltd. All rights reserved.

Materials sciencePhotoemission spectroscopyAnnealing (metallurgy)Fermi levelInverse photoemission spectroscopyAnalytical chemistryAngle-resolved photoemission spectroscopyElectronic structureCondensed Matter Physicssymbols.namesakechemistry.chemical_compoundX-ray photoelectron spectroscopychemistrysymbolsCadmium oxideGeneral Materials ScienceElectrical and Electronic EngineeringAtomic physicsSuperlattices and Microstructures
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